88-65-3 2-Bromobenzoic Acid
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| Brand | CatalogID | Unit | Price($) | Stock (US) | Stock (CN) | Ships within | Quantity | Buy | |||||||||||
| Accela | SY003796 | 25g | 15.00 | in stock | in stock | 1 day | Login | ||||||||||||
| Accela | SY003796 | 100g | 30.00 | in stock | in stock | 1 day | Login | ||||||||||||
| Accela | SY003796 | 500g | 75.00 | 0 | in stock | 3-5 days | Login | ||||||||||||
| Accela | SY003796 | bulk-g | POA | 0 | in stock | 3-5 days | Login | ||||||||||||
| Accela | SY003796 | 1000g | 125.00 | 0 | in stock | 3-5 days | Login | ||||||||||||
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Product InformationSafety InformationReferences
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Forms a dimetallated derivative with n-BuLi, which reacts with electrophiles preferentially at the ortho-carbon: J. Org. Chem., 39, 2051, 2053 (1974); e.g. with aroyl halides leads to 2-carboxybenzophenones which can be cyclized by acid to substituted anthraquinones: J. Org. Chem., 46, 1057 (1981).
The Br can be displaced by malonate-type carbanions, in the presence of Cu catalysts: Angew. Chem. Int. Ed., 13, 340 (1974). For coupling with Na 2,4-pentanedionate, see: Org. Synth. Coll., 6, 36 (1988).
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