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5927-18-4 Trimethyl Phosphonoacetate

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CAS： 5927-18-4 MDL Number： MFCD00008452 MF： C5H11O5P MW： 182.11 Purity： >98% Product Description： Relevant Medicine Name： - COA SDS

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Product InformationSafety InformationReferences

Flash point	70°C(lit.)
Boiling point	108°C/3mmHg(lit.)
Density	1.2620(lit.)
Storage	Light & Moisture sensitive

Horner-Wadsworth-Emmons olefination with aldehydes and ketones gives acrylic esters, cf Triethyl- phosphonoacetate. In general, the (E):(Z) ratio of the resulting alkene increases as the counter-ion becomes smaller (K, Na, Li) and as the temperature increases. See, e.g.: J. Org. Chem., 55, 3386 (1990). Reaction with ɑ-hydroxy ketones provides a simple route to butenolides: Tetrahedron Lett., 36, 2839 (1995).