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4202-14-6 Dimethyl 2-Oxopropylphosphonate

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 CAS:

4202-14-6

 MDL Number: MFCD00008769
 MF: C5H11O4P
 MW: 166.11
 Purity: ≥97%
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    For use of ?-ketophosphonates in an annulation sequence for building a cyclohexadienone ring onto a cyclic ketone, see: Synthesis, 855 (1982).
    Successive treatment with NaH and n-BuLi gives the dianion which can be alkylated or acylated on the terminal position: see. e.g.: Synth. Commun., 22, 219 (1992); J. Chem. Soc., Perkin 1, 2259 (1998).
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