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87-13-8 Diethyl Ethoxymethylenemalonate

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CAS： 87-13-8 MDL Number： MFCD00009148 MF： C10H16O5 MW： 216.23 Purity： ≥98% Product Description： Relevant Medicine Name： - COA SDS

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Product InformationSafety InformationReferences

Flash point	144°(291°F)(lit.)
Boiling point	279-281°C(lit.)
Density	1.080(lit.)
Storage	Light sensitive

Stable equivalent of the ɑ-formylmalonate, valuable synthetic building block, particularly in heterocyclic syntheses. Review: Adv. Het. Chem., 54, (1992). Can be converted to the unstable diethyl methylenemalonate by catalytic reduction and elimination of ethanol on distillation, see: Org. Synth. Coll., 4, 298 (1963). Has been used for the protection of the amino group of ɑ-amino acids, allowing clean esterification by O-alkylation. The protecting group can be removed using bromine in chloroform: Synthesis, 544 (1989). For N-protection of aminoglycosides prior to O-acetylation, see: J. Carbohydr. Chem., 14, 1133 (1995).