6279-86-3 Triethyl Methanetricarboxylate
- * For R&D use only.In Production Stage,Request Bulk Quotation
Brand | CatalogID | Unit | Price($) | Stock (US) | Stock (CN) | Ships within | Quantity | Buy | |||||||||||
Accela | SY018026 | bulk-g | POA | 0 | in stock | 3-5 days | Login | ||||||||||||
SY018026 | 1000g | POA | 0 | in stock | 3-5 days | Login | |||||||||||||
Please Login to see Special Offer & Quantity. | |||||||||||||||||||
Product InformationSafety InformationReferences
Flash point | |
Boiling point | |
Density | |
Storage |
Methanetricarboxylates have been used as "blocked" malonic esters, restricting reaction with alkyl halides to monoalkylation. The unwanted carboxyl group can be removed by treatment with Na alkoxide, LDA or BCl3: J. Org. Chem., 44, 3492 (1979). Adds to Michael acceptors under phase-transfer conditions, providing a useful 2-carbon chain extension method: Synthesis, 1125 (1990).The tricarboxylate also undergoes free-radical addition to the terminal position of alkenes: Angew. Chem. Int. Ed., 5, 586 (1966). Arylation with electron-rich aromatics is promoted by Mn(III): Synthesis, 567 (1991).
Related Products
- SY018028
CAS:138022-02-3
1-Boc-4-[(methylamino)methyl]piperidine - SY018029
CAS:1017356-25-0
1-Boc-3-[(methylamino)methyl]piperidine - SY018037
CAS:172478-01-2
3-(N-Boc-N-methylamino)piperidine - SY018038
CAS:475105-35-2
(S)-2-(Aminomethyl)-1-Boc-piperidine - SY018039
CAS:169447-70-5
(S)-1-Boc-2-Methylpiperazine - SY018040
CAS:923565-98-4
(S)-1-Cbz-2-methylpiperazine - SY018047
CAS:170981-26-7
2-Fluoro-4-methylphenylboronic Acid - SY018052
CAS:129799-08-2
Methyl 4-Boc-piperazine-2-carboxylate