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141556-45-8 1,3-Bis(2,4,6-trimethylphenyl)imidazolium Chloride

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 CAS:

141556-45-8

 MDL Number: MFCD02684541
 MF: C21H25ClN2
 MW: 340.89
 Purity: ≥97%
 Product Description:
 Relevant Medicine Name: -
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In the presence of a base such as KO-t-Bu, generates the imidazol-2-ylidene, an example of an N-heterocyclic carbene (NHC). NHCs are relatively strong bases, and valuable replacements for phosphine ligands in transition metal chemistry. They are relatively stable to dimerization, but sensitive to air and moisture, so are best generated in situ. Review: Angew. Chem. Int. Ed., 36, 2163 (1997). For a review of stable carbenes, see: Chem. Rev., 100, 39 (2000).
Used as a phosphine-free ligand in various metal-catalyzed coupling reactions, often with advantageous results in difficult cases. For use in the Pd-catalyzed cross-coupling of aryl Grignards with aryl chlorides (Kumada reaction), see: J. Am. Chem. Soc., 121, 9889 (1999).
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