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6279-86-3 Triethyl Methanetricarboxylate

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CAS： 6279-86-3 MDL Number： MFCD00009150 MF： C10H16O6 MW： 232.23 Purity： >95% Product Description： Relevant Medicine Name： - COA SDS

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Product InformationSafety InformationReferences

Flash point	>110°
Boiling point	281.3℃ at 760 mmHg
Density	1.095(lit.)
Storage	Regular

Methanetricarboxylates have been used as "blocked" malonic esters, restricting reaction with alkyl halides to monoalkylation. The unwanted carboxyl group can be removed by treatment with Na alkoxide, LDA or BCl3: J. Org. Chem., 44, 3492 (1979). Adds to Michael acceptors under phase-transfer conditions, providing a useful 2-carbon chain extension method: Synthesis, 1125 (1990).
The tricarboxylate also undergoes free-radical addition to the terminal position of alkenes: Angew. Chem. Int. Ed., 5, 586 (1966). Arylation with electron-rich aromatics is promoted by Mn(III): Synthesis, 567 (1991).