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51364-51-3 Tris(dibenzylideneacetone)dipalladium(0)

 CAS:

51364-51-3

 MDL Number: MFCD00013310
 MF: C51H42O3Pd2
 MW: 915.72
 Purity: 95+%
 Product Description:
 Relevant Medicine Name: -
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For use in the coupling of aryl- or vinyltin reagents with allyl halides, see: J. Am. Chem. Soc., 105, 7173 (1983). For Suzuki coupling of boronic acids with carbapenem triflates, see: Tetrahedron Lett., 34, 3211 (1993).
Catalyzes the reduction of terminal allylic acetates or carbonates to 1-alkenes, with virtually complete regioselectivity: Synthesis, 623 (1986).
In the presence of allyl bromide, catalyzes the coupling of terminal alkynes to symmetrical diynes under phase-transfer conditions. The reaction is thought to involve a π-allyl Pd intermediate: Tetrahedron, 52, 1337 (1996).
In the presence of a chelating phosphine ligand and NaO-t-Bu, bromopyridines can be aminated: J. Org. Chem., 61, 7240 (1996).
Catalyst for Stille and Heck coupling reactions in supercritical CO2, in combination with, e.g. Tris[3,5-bis(trifluoromethyl)-phenyl-]phosphine: Chem. Commun., 1397 (1998).
Catalyzes the hydroxycarbonylation of aryl and vinyl halides or triflates by lithium formate, to give carboxylic acids: Org. Lett., 5, 4269 (2003).
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