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1830-54-2 Dimethyl 1,3-Acetonedicarboxylate

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 CAS:

1830-54-2

 MDL Number: MFCD00008462
 MF: C7H10O5
 MW: 174.15
 Purity: >95%
 Product Description:
 Relevant Medicine Name: -
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Reacts with ɑ-diketones in aqueous buffer to give bicyclic diketones (Weiss-Cook condensation): Tetrahedron Lett., 4885 (1968); Org. Synth. Coll., 7, 50 (1990). See also: J. Chem. Soc., Perkin 1, 1425 (1997). Use of cyclic ɑ-diketones leads to propellanes: Can. J. Chem., 189 (1978). The Na salt (NaH/THF) reacts with alkynals: J. Org. Chem., 62, 5688 (1997), or ynones: Synth. Commun., 28, 1525 (1998).
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