3034-53-5 2-Bromothiazole
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Accela | SY001649 | 5g | 10.00 | 0 | in stock | 3-5 days | Login | ||||||||||||
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Accela | SY001649 | 100g | 20.00 | 0 | in stock | 3-5 days | Login | ||||||||||||
Accela | SY001649 | 500g | 75.00 | 0 | 0 | inquire | Login | ||||||||||||
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Product InformationSafety InformationReferences
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2-Lithiothiazole can be obtained by direct lithiation of thiazole or, more conveniently, by exchange with 2-bromothiazole using n-BuLi: J. Org. Chem., 53, 1748 (1988). It behaves as a valuable formyl anion equivalent, and as such has been applied, mainly by Dondoni’s group, in the syntheses of a variety of products; see, e.g.: Tetrahedron Lett., 34, 7319, 7323, 7327 (1993). See also 2-(Trimethyl-silyl)-thiazole. Reaction of 2-lithiothiazole with nitrones gives ɑ-aminoaldehydes: Tetrahedron Lett., 33, 4221 (1992); stereocontrolled addition to C-galacto-pyranosylnitrone has been used in syntheses of destomic acid, a component of the antibiotics destomycin and hygromycin, and of lincosamine, the sugar component of the anticancer antibiotic lincomycin: Synlett, 78 (1993).
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