108448-77-7 (1R)-(+)-2,10-Camphorsultam

Flash point	150.3℃
Boiling point
Density
Storage	Light sensitive

Versatile chiral auxiliary introduced by Oppolzer. Review: Tetrahedron, 49, 293 (1993).
N-Acryloyl derivatives undergo enantioselective cycloaddition reactions: Helv. Chim. Acta, 67, 1397 (1984); Tetrahedron, 43, 1969 (1987). Hydrogenation of N-acryloyl derivatives proceeds with high diastereoselectivity: Tetrahedron Lett., 27, 183 (1986); Helv. Chim. Acta, 69, 1542 (1986), 69, 1817 (1986); 70, 1666 (1987). Induces asymmetric conjugate addition of Grignard reagents to N-acryloyl derivatives: Helv. Chim. Acta, 70, 2201 (1987). In the presence of strong bases, N-acyl derivatives undergo stereoselective alkylation: Tetrahedron Lett., 30, 5603 (1989); or aldol-type condensation reactions with aldehydes: J. Am. Chem. Soc., 112, 2767 (1990); Tetrahedron Lett., 32, 61 (1991).
Chiral auxiliary for the asymmetric Baylis-Hillman reaction: J. Am. Chem. Soc., 119, 4317 (1997).