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12092-47-6 Bis(1,5-cyclooctadiene)dirhodium(I) Dichloride

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 CAS:

12092-47-6

 MDL Number: MFCD00012415
 MF: C16H24Cl2Rh2
 MW: 493.08
 Purity: 98.00-102.00%
 Product Description:
 Relevant Medicine Name: -
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Accela SY001179 0.1g 39.00 - - 2 3 1 day
Accela SY001179 0.25g 92.00 - - 2 0 1 day
Accela SY001179 1g 290.00 - - 2 >5 1 day
Accela SY001179 5g 1010.00 - - 0 4 3-5 days
Accela SY001179 bulk-g POA POA POA - - inquire
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Homogeneous catalyst and catalyst precursor. For use in the preparation of a chiral BINAP alkene isomerization catalyst, see: Org. Synth. Coll., 8, 183 (1993).
Catalyzes the dehydrogenative coupling reaction of styrenes with Pinacolborane, to give the corresponding vinylboronates: Tetrahedron Lett., 40, 2585 (1999); Bull. Chem. Soc. Jpn., 75, 825 (2002). The complex has also been found to promote the atmospheric pressure carbonylation of benzylic halides to give good yields of phenylacetic acids: Tetrahedron Lett., 41, 7601 (2000).
Miyaura has reported the Rh-catalyzed conjugate addition of arylboronic acids to ɑ?-unsaturated carbonyl compounds in a single aqueous phase: Chem. Lett., 722 (2001).
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