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3430-27-1 3-Amino-4-methylpyridine

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CAS： 3430-27-1 MDL Number： MFCD00128871 MF： C6H8N2 MW： 108.14 Purity： ≥98% Product Description： Relevant Medicine Name： - COA SDS

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UN2811 6.1/PG3

Ortho-lithiation with t-BuLi of the Boc-protected amine followed by addition of a Weinreb amide gave the 2-alkyl substituted 5-azaindole in good yield: J. Heterocycl. Chem., 29, 359 (1992), whereas DMF gave 6-azaindole in high yield: Synthesis, 877 (1996). 2-Substituted 6-azaindoles have also been synthesized in one step by direct dilithiation with s-BuLi, followed by reaction with an ester: J. Org, Chem., 70, 6512 (2005).