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3430-27-1 3-Amino-4-methylpyridine

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 CAS:

3430-27-1

 MDL Number: MFCD00128871
 MF: C6H8N2
 MW: 108.14
 Purity: 97+%
 Product Description:
 Relevant Medicine Name: -
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    UN2811 6.1/PG3
    Ortho-lithiation with t-BuLi of the Boc-protected amine followed by addition of a Weinreb amide gave the 2-alkyl substituted 5-azaindole in good yield: J. Heterocycl. Chem., 29, 359 (1992), whereas DMF gave 6-azaindole in high yield: Synthesis, 877 (1996). 2-Substituted 6-azaindoles have also been synthesized in one step by direct dilithiation with s-BuLi, followed by reaction with an ester: J. Org, Chem., 70, 6512 (2005).
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